The task was to intervene on an existing system that no longer met the development needs of the paper mill. The solution was developed by Italprogetti (www. italprogetti. it), deciding to use a type of technology that it had so far applied only in the field of municipal waste water treatment, adapting it in this case to the specific plant characteristics. We're talking about an MBBR (Moving Bed Biofilm Reactor). "With this type of biological treatment," explains Daniele Bacchi, Head of the Waste Water Treatment Sector for Italprogetti, "bacterial colonies - able to clean the water by breaking down the organic matter in it - aren't free to move around in the water; they remain attached to special plastic supports called 'carriers'. These, in turn, are kept in motion inside the reactor thanks to the stirring action of the aeration process whose job is to provide the system with the oxygen needed for the treatment, by injecting compressed air. Special grilles installed in the biological reactor prevent the carriers from emerging along with the treated water. This avoids any risk of biomass loss apart from the excess which, spontaneously detaching itself from the carriers, is then taken away by the biological system.
For tissue mills on the other hand, the type and amount of water and the degree of salinity create different problems from those found in the production of corrugated cardboard. In this case, Italprogetti uses MBR (Membrane Bio Reactor) technology. "We're testing this method in important companies in the field, and obtaining good results" says Daniele Bacchi.
"With this technology, the biomass is suspended with the aid of a traditional biological reactor, but in place of the final sedimenter it has semi-permeable ultrafiltering membranes that separate the treated water and the activated sludge". This means not only an almost three-fold increase in the concentration of activated sludge, but also reduced volumes and ultrafiltered end water. "In practice, MBR technology is both a biological and a tertiary system as it guarantees biological treatment along with highly efficient final filtering that could even allow the direct recycling of the water".This system is ideal even in the case of greater cycle closure; in fact the COD parameters and salinity are suitably treated and reduced - "the first is managed by recycling the water without increasing the COD level in the production cycle, while the goal of further increasing the closure without affecting the salinity (which generally increases during the machine cycle, closing the cycle) is achieved by applying an MBR system followed by reverse osmosis, allowing the recycling of water even when the two parameters have very low values".
"We've renewed an existing water pre-treatment process with a biological solution that meets the needs of the paper mill, thereby creating an efficient new system" says Daniele Bacchi, Head of Italprogetti's Wastewater Treatment Sector.
"This is a decidedly important aspect, especially in the paper industry where the traditional processes with activated sludge with a sedimenter produce sludge flocs that are particularly lightweight and so don't settle well. The risk of dragging the biomass along with the treated water is considerable. "In these conditions, the use of MBR technology (even in the case of running problems, dosing errors, etc.) ensures the persistence of the bacteria in the tank and therefore the recovery of the system, restoring optimum conditions in a short time and reducing the volumes in question by 2 or 3 times compared with traditional technology".
And that's not all. The type of effluent also displayed certain distinguishing aspects: a high inlet COD, a high fraction of organic substances with poor biodegradability, and a high concentration of calcium. "These needs called for not only an MBBR system but also the adoption of other technological solutions to prevent the substantial low-biodegradable fraction from invalidating the outlet COD result and to prevent the calcium from falling onto the carriers, limiting their effectiveness". To resolve the problem, the last of the three MBBR reactors installed in series was given over to the recycling of the activated sludge. "This meant the low-biodegradable fraction of COD could be kept under control, while the calcium level was managed by carefully monitoring the pH in the reactors and dosing a product that prevents it from falling".
The result is a system with capacity rates of 1,000 mᶟ per day, with a COD of about 4,500mg/l on the inlet and 80-100mg/l on the outlet - far below the limit value for the authorisation of discharge in surface waters (160mg/l).
The Italprogetti solution also meets another of Toscopaper's specific needs. Apart from having to choose a technology that reduces the volumes in general, one of the particular features of this intervention was the very limited space available. As Bacchi explains, "that's why we needed a solution with very tall reactors - over 8 metres - for which a traditional technology such as the lobe blower one would have been extremely wasteful in terms of energy. In the end, we opted for two WS 85/3P compressor units of the Robuschi ROBOX SCREW Low pressure range which, thanks to their boosted efficiency, have allowed us to reduce the power levels and so obtain great benefits in relation to system operating costs. The two compressor units each work with a pressure level of 880 mbar, with a capacity of 1,994 Nm3/h at the maximum working point". The Robuschi compressors are oil-free, guaranteeing operation that's even more environmentally friendly (Certification Class 0, in accordance with ISO 8573-1); their minimum sound emissions ensure quiet operation thanks to the high-yield internal compression, silencers and the latest noise enclosures whose simple, sturdy form makes them easy to service.
One of the reasons that make this plant engineering choice ideal for bringing an existing system up to date is its ability to improve and simplify system management, and reduce energy consumption - a goal highlighted by Bacchi himself. "For this purpose, we worked with Robuschi to implement a monitoring of the compressors. The company was able to modify their initial set-up, intervening on the compressor pulleys and belts to optimise their lifespan, maintenance and, above all, energy consumption". The Robuschi compressor, explains the engineer, is a screw solution rather than the traditional lobe blower, "guaranteeing continuous air flow. In addition, there is an inverter which modulates the blower speed according to the concentration of dissolved oxygen in the tank, dispensing just the amount of air strictly needed and keeping the dissolved oxygen at an optimum level, at the same time reducing energy consumption. The screw compressor also allows higher delivery pressure values than the lobe solutions; it's therefore the best choice for vertically developed systems, and can easily be modulated to deal with capacity peaks. But the most interesting aspect is that, especially with significant heights, energy wastage is reduced by approx. 15-20% compared with traditional solutions, depending on the working conditions". A notable advantage that helps ensure a quick economic return on the investment made for the system.
The innovative wastewater treatment system adopted by Toscopaper has been operating successfully since 2013, and the collaboration with its suppliers continues via a constant assistance service. A system check is carried out every 15 days to measure the vital functions; the operators go directly to the plant to personally verify that all the parameters are being met. There's also a remote monitoring system. however.